8/13/2023 0 Comments Signed copy of rumple buttercup![]() ![]() ![]() Join him as he and Candy Corn Carl, his imaginary friend made of trash, learn the joy of individuality as well as the magic of belonging. Rumple Buttercup has five crooked teeth, three strands of hair, green skin, and his left foot is slightly bigger than his right. ![]() Don’t miss this rare collector’s edition of the uplifting 1 New York Times bestseller from Matthew Gray Gubler. Can’t wait to share it with my nieces and nephews. About Rumple Buttercup: A Story of Bananas, Belonging, and Being Yourself Heirloom Edition. Well my copy arrived today and I read it while eating my lunch and I’m not ashamed to say I cried. A charming and inspiring story written and illustrated by Criminal Minds actor/director, Matthew Gray Gubler. I was late to the game and then it was a real hassle to get a copy here, for a reasonable enough price. Rumple Buttercup has five crooked teeth, three strands of hair, green skin, and his left foot is slightly bigger than his right. This is Rumple Buttercup, signed first edition. 9780241383285 Rumple Buttercup: A story of bananas, belonging and being yourself 36.0000 NZD InStock /shop/books /shop/books/childrens-books/picture-books/general /shop/books/childrens-books/picture-books /shop/books/childrens-books /shop/books/teen-young-adult /shop/books/childrens-books/picture-books/favourite-characters A charming and inspiring story, written and illustrated by Criminal Minds actor, Matthew Gray Gubler. ![]()
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8/13/2023 0 Comments Scaphoid bone fracture![]() The above-described mechanism causes the scaphoid bone to impact against the distal radius concavity, causing a fracture most likely to occur in the middle of the scaphoid. This trauma mechanism also puts the dorsal radius and the scaphoid-lunatum (SL) ligament at risk. The typical trauma mechanism is a fall on the outstretched hand with the wrist in radial deviation inducing impact of the palm. In case of a proximal scaphoid fracture, the blood supply through the scaphoid bone is interrupted, making the healing process of the proximal pole particularly more difficult. The proximal pole depends on blood supply from the distal pole through the scaphoid bone. Contrary to the proximal pole, the distal pole and the tubercle have an independent vascularisation. The palmar branch reaches the scaphoid via the distal tubercle. The dorsal branch of the radial artery provides 75% of the blood supply through the foramina. The main blood supply is through retrograde branches of the radial artery. Because of its unique anatomy it can articulate with all five surrounding bones (distal radius, os capitatum, os lunatum, os trapezium and os trapezoideum).Įighty percent of the scaphoid bone consists of cartilage, leaving limited space for entrance of the supplying arteries. The word scaphoid is derived from the Greek word for boat (skaphos). The scaphoid fracture was first described in 1905 by Destot, a French surgeon, anatomist and radiologist. ![]() ![]() ![]() ![]() All is not lost, however: Tax season opens soon, and the IRS still anticipates issuing more than nine out of 10 refunds in less than 21 days. But if it's something more serious, like an offset or credit problem, trying again may not be worth it. It may be that it's something that's fixable (like not having the right documents), and it's worth trying again. If you've been rejected for a refund loan, try reaching out to the company to find out why. Please do your homework and make sure that the company is legitimate before using their services. The IRS has shut some of these companies down, but new ones keep popping up. And many of those companies are honest companies, but not all of them are: some companies are dishonest and intend to deny your loan from the beginning but don't tell you because they want the related tax prep, loan application, credit check, and "junk" fees. And it makes sense that when there's demand, there are going to be companies that step in to fill that need. While I am generally not a fan of RALs, I do recognize that many taxpayers rely on them. The lending or tax prep company is dishonest. Please do not misunderstand/misread/misrepresent my statement. (See Zack Friedman's previous article here.)ĩ. ![]() Even if your identity hasn't been used by another person to file a tax return, if you've been the victim of a data breach and decided to take advantage of a credit freeze, the freeze affects access to your credit information. If your identity has been stolen and used to file a tax return, it will interfere with your ability to file a return and claim a tax refund (and therefore, a loan). You're the victim of identity theft. There may be another reason that you might fail a credit check, even if you have good credit: identity theft. If you always get the same amount, but your tax picture will look a little different this year because of a change in circumstances, your tax preparer may determine that your refund won't support issuing you a loan.Ĩ. If you got married or divorced, had a baby, sent a child off to college, got or lost a job, or even moved to a different state, your tax picture can change. Your personal or financial circumstances have changed. More than tax laws can influence the amount of your tax return: Your personal or financial circumstances can change, too. Being subject to offset can make you a risk to the lender, and they may deny you on that basis.ħ. A credit check, for example, might reveal a student loan delinquency or default, and some municipalities publish notice of parents who are behind on child support payments. This is where those debt indicators used to matter, but even if the absence of a debt indicator, some of the triggers for offset can be discovered using other methods. States can also ask IRS to intercept, or offset, federal tax refunds for state tax debts or money owed to state agencies: this includes child support arrears. Examples of federal obligations that might trigger offsets include federal income tax delinquencies and student loan defaults. That's referred to as "offset" since the seizures are part of the Treasury Offset Program (TOP). You're subject to offset. It has long been the case that if you owe money, your federal income tax refund can be seized to satisfy your debt. Again, your tax preparer knows this, and a lack of earned income could result in a denial.Ħ. If you don't make enough money, your ability to claim certain tax breaks, like refundable credits, could be limited. You didn't make enough money. The crucial part of "earned income tax credit" is "earned income." The amount of the credit is based on earned income - but not unearned income - which means that taxpayers who rely on dividends and interest don't qualify, only those who work for a living. Availability is subject to satisfaction of identity verification, eligibility criteria, and underwriting standards & approval.5. Pre-qualify is ATC application and applicant must undergo additional criteria from provider MetaBank®. ![]() You must first qualify to apply and if pre-qualified you have a higher chance of actual loan/advance approval. Limited time offer at participating locations.Ģ Pre-Qualify application does not guarantee a loan approval. 0 fees - 0% interest! Ask ATC Tax Pro for details. There is no cost to the taxpayer to receive an advance. The Bonu$ is not a "personal loan" and approval is subject to satisfaction of identity verification, eligibility criteria, and underwriting standards. Fees for other optional products or product features may apply. Tax returns may be filed electronically without applying for this loan. The amount of the advance - $200 to $500 - will be deducted from tax refunds and reduce the amount that is paid directly to the taxpayer. 1 $500 Bonu$ – also referred to as Free Tax Loan – is an optional tax refund related loan, not your tax refund, and is via ATC Advance for qualified individuals (Not EML). ![]() 8/13/2023 0 Comments Locking butt plug![]() ![]() Even better than a regular chastity belt though, once locked up the anal plug will give him a constant reminder of what a pathetic excuse for a submissive he is. The firm straps will prevent him getting any access to any of his sexual organs. These are truly the ultimate humiliation for a misbehaving slave. These slaves need a special kind of punishment, and what could be better than a chastity belt containing all the best parts of a cage and a butt plug? Sometimes, no matter what you try, a slave just won’t leave himself alone. Simply tie your ropes to the metal bar connecting the cage to the anal plug, and put him into any uncomfortable position you can imagine! Complete Denial - Chastity Belts with Butt Plugs Take things to the next level by turning it into a bondage butt plug. Both the cage and the anal plug are connected by a solid metal bar, meaning there’s no way he can wriggle out of this one.Ĭompleted with a spacing tube, you can decide exactly how tightly you want your slave to be bound while wearing it. Our “What Do You Peen” cage takes the best of both worlds, and combines them into one torturous experience for your slaves. If having to have a lockable butt plug and a cock cage sounds like too much work, or you’re worried that your slave will still try to find ways to pleasure himself while wearing them, then how about something that combines the two? The easy to handle T-bar base means you can use it to manipulate your slave in any way you could imagine! What Do You Peen? - Cock Cage with Anal Plug It also features a simple to use locking system, which simply requires you to push the stem and lock it in place. Weighing 650g and blooming into an ass-stretching 60mm diameter, your slave is sure to feel this one weighing on his mind. The Stretcher is the premium version of this butt plug. It’s petals expand to an impressive 50mm diameter, which means you can start training his ass to take whatever else you have planned for him. ![]() Weighing in at 350g, it’s not so extreme that your slave will feel huge discomfort. The Nagasaki is our entry level locking anal plug which features the expanding petals. Simply insert the plug as you would a normal butt plug, then open up the petals and lock them in place to make sure they can only remove it when you want them to.īoth of our petal locking butt plugs are made of hard, punishing stainless steel, so your slave won’t feel any mercy while wearing them. ![]() Locking butt plugs that feature a petal design are a great way to really stretch your slave to his limit. Lock that butt too, with a locking butt plug! Spread That Ass - Petal Lockable Butt Plugs Make sure your slave isn’t cheating on his pledge, and having fun when he isn’t supposed to be. Determined slaves can even reach that special-o simply by practising anal and prostate stimulation! Who said chastity was just about stopping a man having fun with his penis? Let’s not forget, the anus is another gateway to pleasure just waiting to be exploited. Don’t just LocktheCock, take your chastity experience to the limit with our range of locking butt plugs! ![]() 8/13/2023 0 Comments Glen hlenn amp concerts![]() Malone has gained international fame for his blend of genres such as hip hop, pop, R&B, trap, and alternative. He’s won multiple awards including 10 Billboard Music Awards, three American Music Awards, a Juno Award, a Pollstar Award, and more. Malone has become one of the best-selling music artists with over 80 million records sold. Billboard 200 and includes hits “Rockstar” and “Psycho.” The album earned Malone his first Grammy Award-nominations for Album of the Year, Record of the Year, Best Rap/ Sung Performance, and Best Pop Solo Performance. ![]() His second album Beerbongs and Bentleys debuted at No. Billboard Top R&B/ Hip Hop Albums Chart with over 70 weeks. The Grammy-nominated artist first began his music career in 2011 gaining recognition for his 2015 hit single “White Iverson.” Malone released his debut album Stoney in 2016 which includes hit single “Congratulations,” setting the record for most weeks on the U.S. It still has not been revealed just how many tracks the record holds, but Malone did admit that he played guitar on every song. The first lead single from the album “Chemical” was released April 14 as a sneak peek of the record. ![]() Days after the announcement, Malone released the second single from the upcoming album “Mourning” attached to a clip of his classic dancing. In his announcement, Malone stated that this is the most exciting record he has worked on as it captures who he is, both as a man and an artist. Post Malone will be celebrating the release of his fifth studio album on the road as Austin will officially drop on July 28. In his announcement via social media Post Malone said that this tour includes “cool new production, new songs, and a very very handsome man up on stage.” This event includes two VIP options both of which include a standard ticket, pre-show VIP lounge with cash bar and snacks, VIP gift item, and more. The tour is set to conclude on August, 19 in San Bernardino, California. ![]() The 24-date tour hits major cities across the North America including Detroit, Toronto, Houston, Phoenix, and others. Our Glen Helen Amphitheater concert schedule is refreshed daily in case their are any adjustments.Singer-songwriter, rapper and record producer Post Malone is embarking on his summer tour on July 8 in Noblesville, IN. Simply view the schedule above for all the upcoming Glen Helen Amphitheater concerts. Glen Helen Amphitheater is one of the most magnificant venues that San Bernardino has to offer. Do not miss some of the concert excitement that Glen Helen Amphitheater has to offer. A selection of music's top tours are about to have concerts at Glen Helen Amphitheater in San Bernardino. Glen Helen Amphitheater currently has a busy list of concert tours visiting the venue in the near future. ![]() These next concerts is going to be some of the most popular Glen Helen Amphitheater concerts by far.Glen Helen Amphitheater is really one of the hottest places for concert tours in San Bernardino.Tickets for all Glen Helen Amphitheater concerts are covered with a 100% moneyback guarantee.Concert Schedule for Glen Helen Amphitheater is refreshed daily.ETickets and last minute tickets for Glen Helen Amphitheater are now available.Glen Helen Amphitheater Concert Information ![]() 8/13/2023 0 Comments C2h4 molecular geometry bond angle![]() ![]() In the case of ethene, there is a difference from, say, methane or ethane, because each carbon is only joining to three other atoms rather than four. It is important that you have first met the idea of hybridisation in the more simple methane case. Use the BACK button on your browser to come back here when you have finished. Note: If you haven't read about bonding in methane, follow this link before you go any further. The carbon atom is now said to be in an excited state. The extra energy released when these electrons are used for bonding more than compensates for the initial input. There is only a small energy gap between the 2s and 2p orbitals, and an electron is promoted from the 2s to the empty 2p to give 4 unpaired electrons. ![]() This is exactly the same as happens whenever carbon forms bonds - whatever else it ends up joined to. The carbon atom doesn't have enough unpaired electrons to form the required number of bonds, so it needs to promote one of the 2s 2 pair into the empty 2p z orbital. Each line in this diagram represents one pair of shared electrons.Įthene is actually much more interesting than this.Įthene is built from hydrogen atoms (1s 1) and carbon atoms (1s 22s 22p x 12p y 1). You may also find it useful to read the article on orbitals if you aren't sure about simple orbital theory.Īt a simple level, you will have drawn ethene showing two bonds between the carbon atoms. It does not store any personal data.Important! You will find this much easier to understand if you first read the article about the bonding in methane. The cookie is set by the GDPR Cookie Consent plugin and is used to store whether or not user has consented to the use of cookies. The cookie is used to store the user consent for the cookies in the category "Performance". This cookie is set by GDPR Cookie Consent plugin. The cookie is used to store the user consent for the cookies in the category "Other. The cookies is used to store the user consent for the cookies in the category "Necessary". The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". The cookie is used to store the user consent for the cookies in the category "Analytics". These cookies ensure basic functionalities and security features of the website, anonymously. Necessary cookies are absolutely essential for the website to function properly. H2O- Bond angles are less than 109.5 degrees (103.9 as analyzed with chime on the class website) which is expected from this molecule’s hybridization. The carbon is sp hybridized and oxygens are sp2 hybridized. There is a double bond between each oxygen and carbon. What is the approximate bond angle in CO2?ĬO2- Bond angles are 180 degrees. As a result of the double bond C 2 H 2 molecular geometry is linear with a bond angle of 180 o.Ī triple bond is the bond that contain one sigma bond and two Pi bond, Acetylene (C2H2) is unsaturated with 2 carbon atoms that are bonded together in a triple bond. Given the distances between 3 atoms, one simple method for calculating bond angles is by use of the trigonometric cosine rule: cosγ = (A2 + B2 − C2) / 2 AB where A, B, C are the lengths of the sides of the triangle ABC, and γ is the angle A-C-B.Įthyne has a triple bond between the two carbon atoms. (A) The structural model for C2H4 consists of a double covalent bond between the two carbon atoms and single bonds to the hydrogen atoms. The 2s orbital in each carbon hybridizes with one of the 2p orbitals and forms two sp hybrid orbitals. In the formation of C2H2, the carbon atom needs extra electrons to form 4 bonds with hydrogen and other carbon atoms. These two orbitals form two pi bonds that result in the formation of triple bonds between carbon atoms. There are two-half filled 2p orbitals for each Carbon atom. Why is C2H2 a triple bond?Ĭ2H2 Hybridization The 1s orbital of the Hydrogen atom overlaps with the Carbon atom’s 2p orbital atom, making it an sp hybridization. Each H-C-H angle is 109.5° and each H-C-C angle is 109.5°. The two carbons are bonded together, and each is bonded to three hydrogens. What is the bond angle of C2H6?Įthane, C2H6, has a geometry related to that of methane. Moreover, carbon is bonding to carbon which gives acetylene (C2H2) a linear structure and a bond angle of 180°. Molecular Geometry of Acetylene (C2H2) Acetylene (C2H2) is a tetra atomic molecule having two different atoms bonding in equal numbers. What is the bond angle of c2h4?ĬCl4 has a tetrahedral geometry with bond angles of 109.5 °. 6 Which type of bond is present in C2H2?.1 How do you find the bond angle of C2H2?. ![]() 8/13/2023 0 Comments Succubus hentai game![]() We has set up some stunning succubus sex game. In the event that you assumed other succubus porn game ended up joy, you've never discovered such a thing but! On the idea where pornography gaming sites also suggest manga porn or manga porno. 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8/13/2023 0 Comments Geometry dash lite pc![]() ![]() Hence they have intricately designed features that would not only enhance your game performance but enable you to take control of your game time efficiently. ![]() To every gamer’s excitement, the developers of BlueStacks have taken into cognizance the benefits of an app that gives smooth and efficient game plays. You can open different tabs on your PC, play different games, or switch between working and gaming without experiencing any glitch in screen performance. Watch out for weekly or monthly updates on new levels and enjoy playing this game on PC.ĭownload Geometry Dash Meltdown using BlueStacks 5 on at least a 4GB RAM PC to experience efficient multitasking. Go into the practice zone to sharpen your mind as well as your coordination. Also, collect boosters to help you when you get stuck. Unlock game icons and colors to customize your game character. With three awesome but difficult levels to scale through, stay hooked for long hours playing this game to ensure you survive. Somersault, bounce, or fly rockets to ensure you do not land into the fire or the spikes. Bypass every obstacle by every means possible. Have your cube flip and jump through very difficult loops and land on its feet unscathed. In this game, challenge yourself to do almost impossible. Are you ready to play? Download Geometry Dash Meltdown on PC now. Jump through loops, flip over the fire and fly your way out of the carven. BlueStacks app player is the best platform to play this Android game on your PC or Mac for an immersive gaming experience.ĭownload Geometry Dash Meltdown on PC and defile the laws of gravity as you escape from terrifying obstacles and dangers. Play our great free games on your desktop PC and laptop as well as your netbook and Windows Tablet PC.To download these games,software or apps,you need to download the best android emulator: Nox App Player or Xeplayer first.Geometry Dash Meltdown is an arcade game developed by RobTop Games. You can download Apk Apps and Games for Windows 10, Windows 8, Windows 7, Windows Vista, and Windows XP. ![]() All of our free downloadable games are 100% free of malware and viruses. Download and play racing games,3d action games, car games, bike games, 3d games,shooting games,fighting games,adventure games,hidden object games and train simulator games,gta vice city games. ![]() Welcome to ,the source of the best download free games.This is one of the best places on the Web to play new PC/Laptop games for free in 2019!Our games are licensed Full Version PC Games. PC Games And PC Apps Free Download Full Vesion For Windows 7,8,10,XP,Vista and Mac.Download and play these top free PC Games,Laptop Games,Desktop Games,Tablet Games,Mac Games.Also you can download free software and apps for PC (Windows 7,8,10,XP,Vista) and Mac. Well done! Now you can play Geometry Dash Lite on PC, just like Geometry Dash Lite for PC version. Open Google Play Store and search Geometry Dash Lite Download Run Nox App Player Android Emulator and login Google Play Store Game FeaturesRhythm-based Action Platforming!Unlock new icons and colors to customize your character!Fly rockets, flip gravity and much more!Use practice mode to sharpen your skills!Challenge yourself with the near impossible!Ĭontact: How to play Geometry Dash Lite on PCĭownload and Install Nox App Player Android Emulator. Simple one touch game play that will keep you entertained for hours!Ĭheck out the full version for new levels, soundtracks, achievements, online level editor and much much more! Push your skills to the limit as you jump, fly and flip your way through dangerous passages and spiky obstacles. Prepare for a near impossible challenge in the world of Geometry Dash. Jump and fly your way through danger in this rhythm-based action platformer! ![]() 8/12/2023 0 Comments 8x10 home office layout![]() ![]() Interior designer Barbara Hayman, who also works with Decorating Den, notes that the quartet of privacy, storage, cord management, and lighting need to be considered for every home work space, no matter how it will be used. “Are you using it for your personal life? Will your job be out of the office? Will you have clients come in? What about kids?” and Canada, says the first step in determining how to lay out a home office is to better understand how your needs can be met in the available square footage. Interior designer Dee Frazier, who works with Decorating Den Interiors, a network of individually owned and operated interior design franchises throughout the U.S. To ensure your space is working as hard and efficiently as you are, it’s important to design the office with a few key principles in mind. ![]() Once you're satisfied that your home office design ideas are going to work, connect and test all equipment to make sure everything's working properly, that all cords are long enough, and that you haven't overloaded any circuits.But now, with remote work and virtual school being the norm for families across the United States, the home office has become one of the most important, and most coveted, rooms of the house. Accessing files and supplies needs to be an easy chore so you'll spend less time doing it and more time working. Your work area needs to function efficiently so you can be more productive. A few adjustments now will save you grief later. Your home office design ideas may have seemed great, but when you go to set up your office at home you might find they really don't work well for you. Make one last check to be sure you're happy with the layout and that it will serve you well in the days ahead.Add desk accessories to help you stay productive and organized.Add bulletin boards, whiteboards and other organizational wall items.If needed, clean or dust them as you place them in the room. Bring in smaller items to complete the set up of your office at home, such as lamps, organizers and desktop items.Sit in your desk chair and take in the view. ![]() Before connecting everything, make sure you're still happy with your home office design ideas, especially the layout of your work area and that no unexpected problems have cropped up – such as a monitor screen receiving too much glare from a nearby window, or your desk area not receiving adequate light.As you place each piece, check to see if it needs to be cleaned, oiled, or otherwise serviced, and that all cords are long enough to reach your outlets or power strips. Bring in your home office equipment and place it where it needs to go in the room.As you set up your office and bring in furniture, dust, and polish it as needed. It's best to start with the larger pieces first so you'll still have the maximum amount of floor space to move them around. Bring furniture into your office space.For assistance, see the Home Office Furniture Plans step in this series. However, while you don't want the furniture in the way at this stage of setting up your home office, you'll want to make sure you know exactly where your furniture and equipment will be placed in the room. Without furniture and equipment to get in your way, this step can be completed much more quickly and easily. before bringing anything into the new space. Thoroughly clean and paint, wallpaper, add floor coverings, hang light fixtures, etc.Install any electrical, phone or cable outlets, cabinetry, shelving, and/or wall partitions on your plan - ideally while the space is already empty.that are not part of your new home office design ideas. If you need some remodeling done to accommodate your home office set up, the next step will be demolition to remove existing partitions, shelving, etc.This will help you start with a blank canvas that you'll fill in with your home office design ideas one step at a time. If you're converting a closet, remove all clothing and other items from the closet. If practical, remove any existing furniture and plants from the room or space that you will set up as your home office. ![]() 8/12/2023 0 Comments Crossbow broadheads![]() ![]() The steel ferrule with chisel tip is strong and durable, ensuring that the broadhead can withstand impact and penetrate deeply.The offset fixed blades induce spin, which helps increase accuracy and stability.The 1-inch fixed blade cutting diameter and 1 5/8-inch expandable cutting diameter make it easy to take down large game.If you’re looking for a reliable and effective crossbow broadhead, the Muzzy Trocar HBX Crossbow Archery Arrow Hybrid Broadhead is definitely worth considering. Muzzy Trocar HBX Crossbow Archery Arrow Hybrid Broadhead So, whether you’re a seasoned hunter or a beginner, we’ve got you covered. Our team has spent hours researching and testing different products to bring you this comprehensive list. That’s why we’ve put together a list of the best crossbow broadheads that will help you make an informed decision. With so many options available on the market, it’s hard to know which one is the best for your specific needs. We know that choosing the right crossbow broadhead can be a daunting task. With our expert guidance, you’ll be able to choose the right crossbow broadheads for your needs and take your hunting game to the next level. We spent countless hours researching and testing ten of the best crossbow broadheads on the market to identify the ones that offer the perfect balance of accuracy, penetration, and lethality. When choosing a crossbow broadhead, it’s important to consider factors such as weight, blade design, and cutting diameter. Fixed blade broadheads are known for their simplicity and durability, while mechanical broadheads offer greater accuracy and penetration. There are two main types of crossbow broadheads: fixed blade and mechanical. However, to get the most out of your crossbow, you need to equip it with the right gear, and that includes choosing the best crossbow broadheads.Ĭrossbow broadheads are the tips that attach to the end of your arrows and are responsible for delivering a clean and humane kill. Crossbows offer a unique hunting experience that combines the accuracy and power of a firearm with the challenge of traditional archery. Crossbow hunting has become increasingly popular in recent years, and for good reason. ![]() |
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